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 Platinum - Definition 

Platinum is also a certification by the RIAA and other world recording industries, see: RIAA certification
Iridium - Platinum - Gold
Pd
Pt
Ds
image:Pt-TableImage.png
General
Name, Symbol, Number Platinum, Pt, 78
Chemical series transition metals
Group, Period, Block 10 , 6, d
Density, Hardness 21.45 Mg/m³, 3.5
Appearance
grayish white
Atomic properties
Atomic weight 195.078 g/mol
Atomic radius (calc.) 135 (177) pm
Covalent radius 128 pm
van der Waals radius 175 pm
Electron configuration [Xe]4f145d96s¹
e- 's per energy level 2, 8, 18, 32, 17, 1
Oxidation states (Oxide) 2, 4 (mildly basic)
Crystal structure Cubic face centered
Physical properties
State of matter solid (paramagnetic)
Melting point 2041.4 K (3214.9 °F)
Boiling point 4098 K (6917 °F)
Molar volume 9.09 cm³/mol
Heat of vaporization 510 kJ/mol
Heat of fusion 19.6 kJ/mol
Vapor pressure 0.0312 Pa at 2045 K
Speed of sound 2680 m/s at 25 °C
Miscellaneous
Electronegativity 2.28 (Pauling scale)
Specific heat capacity 130 J/(kg·K)
Electrical conductivity 9.66 MS/m
Thermal conductivity 71.6 W/(m·K)
1st ionization potential 870 kJ/mol
2nd ionization potential 1791 kJ/mol
Most stable isotopes
<td>0.01%
iso NA half-life DM DE fJ DP
190Pt6.5 E11 y α 520.5 186Os
192Pt 0.79% Pt is stable with 114 neutrons
193Pt {syn.} 50 y ε 9.1 193Ir
194Pt 32.9% Pt is stable with 116 neutrons
195Pt 33.8% Pt is stable with 117 neutrons
196Pt 25.3% Pt is stable with 118 neutrons
198Pt 7.2% Pt is stable with 120 neutrons
SI units & STP are used except where noted.

Platinum is a chemical element in the periodic table that has the symbol Pt and atomic number 78. A heavy, malleable, ductile, precious, gray-white transition metal, platinum is resistant to corrosion and occurs in some nickel and copper ores along with some native deposits. Platinum is used in jewelry, laboratory equipment, electrical contacts, dentistry, and anti-pollution devices in automobiles.

Contents

Notable characteristics

The metal is a beautiful silvery-white when pure, and malleable and ductile. The metal is corrosion-resistant. The catalytic properties of the six platinum family metals are outstanding (a mixture of hydrogen and oxygen explodes in the presence of platinum). Platinum's wear- and tarnish-resistance characteristics are well-suited for making fine jewelry.

Other distinctive properties include resistance to chemical attack, excellent high-temperature characteristics, and stable electrical properties. All these properties have been exploited for industrial applications. Platinum does not oxidize in air at any temperature but can be corroded by cyanides, halogens, sulfur, and caustic alkalis. This metal is insoluble in hydrochloric and nitric acid but does dissolve when mixed as aqua regia (forming chloroplatinic acid). Common oxidation states of platinum include +2, +3, and +4.

Applications

Platinum is used extensively in jewelry, wire, in making crucibles for chemical use and for constructing high-temperature electric furnaces. Finely divided platinum is often used as a chemical catalyst. For example, platinum is used in catalytic converters for automobiles and in various industrial processes. Formerly, platinum was used in the manufacture of sulfuric acid. Other uses:

  • The metal can absorb large quantities of hydrogen gas and will release it when heated. It is therefore been studied as a possible storage medium for the gas for use in fuel cell vehicles.
  • The chemical industry uses a significant amount of either platinum or a platinum-rhodium alloy catalyst in the form of gauze to catalyze the partial oxidation of ammonia to yield nitric oxide, which is the raw material for fertilizers, explosives, and nitric acid.
  • Platinum-supported catalysts are used in the refining of crude oil, reforming, and other processes used in the production of high-octane gasoline and aromatic compounds for the petrochemical industry.
  • This metal has a coefficient of thermal expansion that is almost equal to that of soda-lime-silica glass and is therefore used to make sealed electrodes in glass systems.
  • Alloys of platinum and cobalt have excellent magnetic properties. One alloy that has 76.7% Pt and 23.3% Co, by mass, forms an extremely powerful magnet.
  • 90/10 Platinum/osmium alloy is used to make pacemakers, replacement valves and other surgical implants.
  • Used for coating missile nose cones, jet engine fuel nozzles, and other devices which must perform reliably at high temperatures for extended periods of time.
  • Fine platinum wire glows red hot when exposed to methyl alcohol vapor acting as a catalyst that converts the alcohol to formaldehyde. This phenomenon has been commercially used to make cigarette lighters and hand warmers.
  • Cis-platin (http://www.nlm.nih.gov/medlineplus/druginfo/medmaster/a684036.html), [PtCl2(NH3)2] and Carboplatin are some of the drugs that are very effective in treating certain types of cancer which include leukemia and testicular cancer.

History

The name platinum derives from the Spanish platina meaning "little silver".

Naturally-occurring platinum and platinum-rich alloys have been known for a long time. Though the metal was used by pre-Columbian Indians, the first European reference to platinum appears in 1557 in the writings of the Italian humanist Julius Caesar Scaliger (1484-1558) as a description of a mysterious metal found in Central American mines between Darién (Panama) and Mexico ("up until now impossible to melt by any of the Spanish arts").

The Spaniards named the metal "platina," or little silver, when they first encountered it in Colombia. They regarded platinum as an unwanted impurity in the silver they were mining, and often discarded it.

Platinum was discovered by astronomer Antonio de Ulloa and Don Jorge Juan y Santacilia (1713-1773), both appointed by King Philip V to join a geographical expedition in Peru that lasted from 1735 to 1745. Among other things, Ulloa observed the platina del pinto, the unworkable metal found with gold in New Granada (Colombia). British privateers intercepted Ulloa's ship on the return voyage. Though he was well-treated in England, and even made a member of the Royal Society he was prevented from publishing a reference to the unknown metal until 1748. Before that could happen Charles Wood independently isolated the element in 1741.

Alchemical symbol for platinum
The alchemical symbol for platinum (shown on the right) was made by joining the symbols of silver and gold.

Platinum is now considered more precious than gold, so that a platinum award is better than a golden one. The price of platinum changes along with its availability, but it normally costs about twice as much as gold.

The standard definition of a metre for a long time was based on the distance between two marks on a bar of a platinum-iridium alloy housed at the Bureau International des Poids et Mesures in Sevres, France. A platinum-iridium cylinder serves to this day as the standard of the kilogram and is housed in the same facility as the metre bar. Platinum is also used in the definition of the Standard hydrogen electrode.

Occurrence

Platinum ore
Enlarge
Platinum ore

Platinum is often found in a native state and the ore sperrylite (platinum arsenide, PtAs2) is a major source of the metal. A naturally occurring platinum/iridium alloy is platiniridium and this metal is also found in the mineral cooperite (platinum sulfide, PtS).

This metal is often accompanied by small amounts of other platinum family metals which are found in alluvial deposits in Colombia, Ontario, the Ural Mountains, and in certain western American states.

Platinum is produced commercially as a by-product of nickel ore processing. The huge quantities of nickel ore processed makes up for the fact that platinum makes up only two parts per million of the ore.

The Anglo Platinum Group ( http://www.angloplatinum.com ) is the world's leading primary producer of platinum group metals from it's South African mines. They mine, process, refine and market platinum group metals as its main products.

Isotopes

Naturally occurring platinum is composed of five stable isotopes and one radioisotope, Pt-190, which has a very long half-life (over 6 billion yearsor 190 Ps). There are also many other radioisotopes with the most stable being Pt-193 with a half-life of 50 years.

Precautions

This metal doesn't normally cause health problems due to its unreactive nature but all compounds of platinum should be considered to be highly toxic. Platinum compounds rarely occur in nature.

References

External links



ca:Platí cs:Platina de:Platin eo:Plateno es:Platino et:Plaatina fr:Platine ia:Platino it:Platino ja:プラチナ nl:Platina pl:Platyna pt:Platina (elemento químico) ru:Платина simple:Platinum sl:platina sv:Platina

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This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Platinum".