Propanal Propanal

Propanal - Definition

Properties

General

Name Propanal
Chemical formula CH3CH2CHO
Formula weight 58.08 amu
Synonyms Propionaldehyde, methylacetaldehyde, propionic aldehyde, propaldehyde
CAS number 123-38-6
UN number 1275

Phase behavior

Melting point 192 K (-81°C)
Boiling point 321 K (48°C)
Triple point 171 K (-102°C)


? bar

Critical point  ?


? bar

ΔfusH 8.59 kJ/mol
ΔfusS  ? J/mol·K
ΔvapH 28.3 kJ/mol
Solubility 50-100 mg/ml

Liquid properties

ΔfH0liquid  ? kJ/mol
S0liquid  ? J/mol·K
Cp  ? J/mol·K
Density 0.81 ×103 kg/m3

Gas properties

ΔfH0gas  ? kJ/mol
S0gas J/mol·K
Cp  ? J/mol·K

Safety

Acute effects Respiratory irritation, dizziness, skin irritation.
Chronic effects Pulmonary oedema; mutagenic effects have been reported.
Flash point -26°C
Autoignition temperature 175°C
Explosive limits 2.3-21%

More info

Properties NIST WebBook (http://webbook.nist.gov/cgi/cbook.cgi?ID=123-38-6&Units=SI)
MSDS Hazardous Chemical Database (http://ull.chemistry.uakron.edu/erd/chemicals1/7/6976.html)

SI units were used where possible. Unless otherwise stated, standard conditions were used.

Disclaimer and references

In organic chemistry, propanal or propionaldehyde is the aldehyde of the 3 carbon propyl group. It has a chemical formula of CH3CH2CHO, and is a structural isomer of propanone. At room temperature, it is a colourless liquid with a slightly irritating, fruity odour.

Production

Propanal is mainly produced through the Fischer-Tropsch synthesis, combining synthesis gas (carbon monoxide and hydrogen) with ethene over a metal catalyst:

CO + H2 + C2H4 → CH3CH2CHO

Uses

It is principally used to make trimethylolethane through condensation with methanol; this process is important in the production of alkyd resins.

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